The only way I am able to duplicate the original plot is, as @sconfluentus noted, for the 7% and 21% to be character strings. As an aside the data frame column names need not be quoted.
df= data.frame(number = c('7%','21%'), name = c("x","y"))
df
ggplot(df, aes(x=name, y=number)) +
geom_bar(stat="identity", fill = "blue") + xlab("Title") + ylab("Title") +
ggtitle("Title")

Changing the numbers to c(0.07, 0.21)
and adding, as @Mohanasundaram noted, scale_y_continuous(labels = scales::percent)
corrects the situation:

To be pedantic using breaks = c(0.07, 0.21)
creates nearly an exact duplicate. See also here.3
Hope this is helpful.
library(ggplot2)
library(scales)
df= data.frame(number = c(0.07,0.21), name = c("KG","MS"))
df
ggplot(df, aes(x=name, y=number)) +
geom_bar(stat="identity", fill = "blue") + xlab("Title") + ylab("Title") +
ggtitle("Title") + scale_y_continuous(labels = scales::percent, breaks = c(.07, .21)))
